Phenazine–naphthalene-1,5-diamine–water (1/1/2)

Phenazine–naphthalene-1,5-diamine–water (1/1/2)

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ULT DIGESTIVE IMMED REL The asymmetric unit of the title compound, C12H8N2·C10H10N2·2H2O, contains one half-molecule of phenazine, one half-molecule of naphthalene-1,5-diamine and one water molecule.The phenazine and naphthalene-1,5-diamine molecules are located on inversion centers.The water molecules serve as bridges between the naphthalene-1,5-diamine molecules and also between the naphthalene-1,5-diamine and phenazine molecules.The naphthalene-1,5-diamine and water molecules are connected via N—H.O and O—H.

N hydrogen bonds, forming a T4(2) motif.They are arranged into a two-dimensional polymeric structure parallel to (10overline{1}) in which the water molecule is a single donor and a double acceptor, whereas the amino group is a double donor and a single acceptor in the hydrogen bonding.These two-dimensional assemblies alternate with the layers of phenazine molecules arranged into a herringbone motif.Each phenazine molecule is hydrogen bonded to two water molecules and thus a Wheel Spacer three-dimensional framework of hydrogen-bonded molecules is generated.